6.1 Cooling Water treatment



Types of cooling system

·         1. Open re-circulation system

·          2. Once through system

·          3. Closed re-circulation system


Cooling Water is the water that is circulated through the equipment to absorb and carry away the heat. The objective of cooling water treatment are-

  1. ·         Control of corrosion
  2. ·         Control of scale
  3. ·         Control of fouling

 

A

Factors for Corrosion

 

Control of corrosion

 

Material of Construction

 

Selecting proper MOC of cooling equipment such as- carbon steel, admiralty brass, cupronickel alloy and stainless steel.

 

Design and fabrication of the heat exchanger and surface condensers.

 

-Providing horizontal cut baffles in place of vertical cut baffles.

-Provision for venting the non condensates accumulated in the HE system.

-Provision for draining the coolers.

-Provision for air bumping

-Provision for back flushing arrangement.

 

The corrosion of mild steel increase with the increase in the level of Dissolved Oxygen.

 

Passivation of metal surface

 

The corrosion rate increases at lower pH.

 

By proper cooling water treatment

 

Total Dissolved Solid hikes up electrical conductivity of the solution thereby creating a corrosive environment.

 

TDS level to be maintained by proper blow down.

 

The corrosion rate increases with increase in Temperature.

 

Temperature to be maintained as per design value.

 

An increase in rate of C/W flow generally tends to increase the rate of corrosion.

 

C/W flow to be maintained as per design value.

 

Microbiological Corrosion

 

By proper cooling water treatment

 

B

Factors for Scale formation in C/W

 

Control of Scale

 

Calcium carbonate

Calcium Phosphate

Zink Phosphate

Calcium sulphate

Magnesium salts

Silica

 

Acid Treatment

Antiscalent

 

C

Fouling

 

Control of fouling

 

When any undesirable material is deposited on a heat exchanger surface, it is called fouling-

Precipitation fouling

Particulate fouling

Chemical reaction fouling

Corrosion fouling

Biological fouling

Freezing fouling

 

By proper cooling water treatment



Types of Cooling Water Treatment:

  • 1.    Biocide treatment - To kill the algae and rapture the algal material.
  • 2.    Chlorine treatment - To Kill Bacteria. Bacteria converts dissolved ammonia to NO which is converted to NO2 by nitrifying bacteria. The latter is acidic in aqueous layer causing corrosion.
  • 3.    Alkali/Acid treatment
  • 4.    Phosphate treatment
  • 5.    Chromate treatment



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